Acidic strength is directly proportional to -I effect and inversion-ally proportional to +I effect.







Example:
a. H3C-CH2-COOH      >       (CH3)2-CH-COOH       >       (CH3)3-C-COOH
                               +I Effect increases
          ========================================>
                             So, acidic strength decreases

b.   Cl3C-CH2-COOH      >     Cl2HC-CH-COOH      >      ClH2C-C-COOH
                               -I Effect decreases
         =========================================>
                         So, acidic strength decreases


c. CH3-CH2-CHF-COOH     >     CH3-CHF-CH2-COOH   >   F-(CH2)3-COOH

             Distance of Fluorine atom increases so, -I Effect decreases
         ==========================================>
                         That’s why acidic strength decreases


d. COOH-COOH    >    COOH-CH2-COOH   >   COOH-CH2-CH2-COOH
   {Oxalic acid}               {Malonic acid}                 {Succinic acid}
         ==========================================>
              +I Effect increases so, acidic strength decreases

e. CH3-(CH2)2-COOH   <    CH2=CH-CH3-COOH   <   CH≡C-CH2-COOH
          ===================================================>
                   -I Effect increases
                S-Character increases 
                So, EN increases 
                So, -ve charge decreases 
                   That’s why stability increases



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